Title: Water Formation in the Early Universe Author: Shmuel Bialy, Amiel Sternberg, Abraham Loeb
We demonstrate that high abundances of water vapour could have existed in extremely low metallicity (10-3 solar) partially shielded gas, during the epoch of first metal enrichment of the interstellar medium of galaxies at high redshifts.
University of Utah chemists may have solved one enigma by showing how cold water can get before it absolutely must freeze: 55 degrees below zero Fahrenheit. That's 87 degrees Fahrenheit colder than what most people consider the freezing point of water, namely, 32 F. Supercooled liquid water must become ice at minus 55 F (-48°C) not just because of the extreme cold, but because the molecular structure of water changes physically to form tetrahedron shapes, with each water molecule loosely bonded to four others, according to the new study by chemists Valeria Molinero and Emily Moore. Read more
Strange, stranger, strangest! To the weird nature of one of the simplest chemical compounds - the stuff so familiar that even non-scientists know its chemical formula - add another odd twist. Scientists are reporting that good old H2O, when chilled below the freezing point, can shift into a new type of liquid. The report appears in ACS' Journal of Physical Chemistry B. Pradeep Kumar and H. Eugene Stanley explain that water is one weird substance, exhibiting more than 80 unusual properties, by one count, including some that scientists still struggle to understand. For example, water can exist in all three states of matter (solid, liquid,gas) at the same time. And the forces at its surface enable insects to walk on water and water to rise up from the roots into the leaves of trees and other plants. In another strange turn, scientists have proposed that water can go from being one type of liquid into another in a so-called "liquid-liquid" phase transition, but it is impossible to test this with today's laboratory equipment because these things happen so fast. That's why Kumar and Stanley used computer simulations to check it out. They found that when they chilled liquid water in their simulation, its propensity to conduct heat decreases, as expected for an ordinary liquid. But, when they lowered the temperature to about 54 degrees below zero Fahrenheit, the liquid water started to conduct heat even better in the simulation. Read more
One of the most interesting molecules that astronomers like to study is water, which is so abundant on the Earth and though to be crucial for life. Water can form relatively easily, providing the temperature is not too high, and the outer regions of our own Solar system are full of icy bodies. Observations of water are very hard to observed from the Earth as the atmosphere interferes with the measurements, and so studying water requires spacecraft. Far from Earth, the HIFI instrument on board Herschel is studying the role of water in not just our own Solar System, but also in others. Read more
Electric ice may pervade space. This strange form of water is more persistent than was previously thought, and the discovery could change our understanding of how the solar system formed. It might even give ice a new role in the emergence of the complex organic molecules needed for life. In a single molecule of water - H2O - there is a charge separation. That's because the two positively charged hydrogen atoms cluster at one end, away from the single negatively charged oxygen. However, the charges get mixed up when ordinary ice, known as ice Ih, forms. While the oxygen atoms arrange themselves in a repeating pattern, the pairs of hydrogen atoms that extend from them don't. Instead, they randomly take one of a number of positions Read more
The secret life of water just got weirder. For years water has been known to exist in 15 phases - not just the merry threesome of solid, liquid and gas from grade school science. Now, University of Utah chemists have confirmed the coexistence of ice and liquid after water crystallises at very low temperatures. They describe their work in the June 21 issue of the Journal of Chemical Physics, which is published by the American Institute of Physics (AIP). Read more
Amorphous ice is an ice lacking crystal structure. Amorphous ice exists in three forms: low-density (LDA) formed at atmospheric pressure, or below, high density (HDA) and very high density amorphous ice (VHDA), forming at higher pressures. LDA forms by extremely quick cooling of liquid water ("hyperquenched glassy water", HGW), by depositing water vapour on very cold substrates ("amorphous solid water", ASW) or by heating high density forms of ice at ambient pressure ("LDA").
A metastable cubic crystalline variant of ice. The oxygen atoms are arranged in a diamond structure. It is produced at temperatures between 130 and 220 K, and can exist up to 240 K, when it transforms into ice Ih. It may occasionally be present in the upper atmosphere.
A rhombohedral crystalline form with highly ordered structure. Formed from ice Ih by compressing it at temperature of 190-210 K. When heated, it undergoes transformation to ice III.
A metastable rhombohedral phase. It can be formed by heating high-density amorphous ice slowly at a pressure of 810 MPa. It doesn't form easily without a nucleating agent.
Ice V
A monoclinic crystalline phase. Formed by cooling water to 253 K at 500 MPa. Most complicated structure of all the phases.
Ice VI
A tetragonal crystalline phase. Formed by cooling water to 270 K at 1.1 GPa. Exhibits Debye relaxation.
A tetragonal phase. Formed gradually from ice III by cooling it from 208 K to 165 K, stable below 140 K and pressures between 200 MPa and 400 MPa. It has density of 1.16 g/cm3, slightly higher than ordinary ice.
Ice X
Proton-ordered symmetric ice. Forms at about 70 GPa.
Ice XI
An orthorhombic, low-temperature equilibrium form of hexagonal ice. It is ferroelectric. Ice XI is considered the most stable configuration of ice Ih. The natural transformation process is very slow and ice XI has been found in Antarctic ice 100 to 10,000 years old. That study indicated that the temperature below which ice XI forms is -36 °C (240 K).
A tetragonal, metastable, dense crystalline phase. It is observed in the phase space of ice V and ice VI. It can be prepared by heating high-density amorphous ice from 77 K to about 183 K at 810 MPa.
Ice XIII
A monoclinic crystalline phase. Formed by cooling water to below 130 K at 500 MPa. The proton-ordered form of ice V.
Ice XIV
An orthorhombic crystalline phase. Formed below 118 K at 1.2 GPa. The proton-ordered form of ice XII.