Title: Atmospheric Constraints on the Surface UV Environment of Mars at 3.9 Ga Relevant to Prebiotic Chemistry Author: Sukrit Ranjan, Robin D. Wordsworth, Dimitar D. Sasselov
Recent findings suggest Mars may have been a clement environment for the emergence of life, and may even have compared favourably to Earth in this regard. These findings have revived interest in the hypothesis that prebiotically important molecules or even nascent life may have formed on Mars and been transferred to Earth. UV light plays a key role in prebiotic chemistry. Characterizing the early Martian surface UV environment is key to understanding how Mars compares to Earth as a venue for prebiotic chemistry. Here, we present two-stream multi-layer calculations of the UV surface radiance on Mars at 3.9 Ga, to constrain the surface UV environment as a function of atmospheric state. We explore a wide range of atmospheric pressures, temperatures and compositions, corresponding to the diversity of Martian atmospheric states consistent with available constraints. We include the effects of clouds and dust. We calculate dose rates to quantify the effect of different atmospheric states on UV-sensitive prebiotic chemistry. We find that for normative clear-sky CO2-H2O atmospheres, the UV environment on young Mars is comparable to young Earth. This similarity is robust to moderate cloud cover: thick clouds (tau>100) are required to significantly affect the Martian UV environment, because cloud absorption is degenerate with atmospheric CO2. On the other hand, absorption from SO2, H2S, and dust is nondegenerate with CO2, meaning if they can build up to high levels, surface UV fluence will be suppressed. These absorbers have spectrally variable absorption, meaning that their presence affects prebiotic pathways in different ways. In particular, high SO2 environments may admit UV fluence that favours pathways conducive to abiogenesis over pathways unfavourable to it. However, better measurements of the spectral quantum yields of these pathways are required to evaluate this hypothesis definitively.
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Mars: Red Planet's Rapid Formation Explains Its Small Size Relative to Earth
Mars developed in as little as two to four million years after the birth of the solar system, far more quickly than Earth, according to results of a new study published in this week's issue of the journal Nature. The red planet's rapid formation helps explain why it is so small, say the study's co-authors, Nicolas Dauphas at the University of Chicago and Ali Pourmand at the University of Miami. Their research was funded by the National Science Foundation (NSF). Read more