MIT scientists have brought a supercool end to a heated race among physicists: They have become the first to create a new type of matter, a gas of atoms that shows high-temperature superfluidity.
Their work, to be reported in the June 23 issue of Nature, is closely related to the superconductivity of electrons in metals. Observations of superfluids may help solve lingering questions about high-temperature superconductivity, which has widespread applications for magnets, sensors and energy-efficient transport of electricity, said Wolfgang Ketterle, a Nobel laureate who heads the MIT group and who is the John D. MacArthur Professor of Physics as well as a principal investigator in MIT's Research Laboratory of Electronics.
Seeing the superfluid gas so clearly is such a dramatic step that Dan Kleppner, director of the MIT-Harvard Centre for Ultracold Atoms, said, "This is not a smoking gun for superfluidity. This is a cannon."
For several years, research groups around the world have been studying cold gases of so-called fermionic atoms with the ultimate goal of finding new forms of superfluidity. A superfluid gas can flow without resistance. It can be clearly distinguished from a normal gas when it is rotated. A normal gas rotates like an ordinary object, but a superfluid can only rotate when it forms vortices similar to mini-tornadoes. This gives a rotating superfluid the appearance of Swiss cheese, where the holes are the cores of the mini-tornadoes. "When we saw the first picture of the vortices appear on the computer screen, it was simply breathtaking," said graduate student Martin Zwierlein in recalling the evening of April 13, when the team first saw the superfluid gas. For almost a year, the team had been working on making magnetic fields and laser beams very round so the gas could be set in rotation. "It was like sanding the bumps off of a wheel to make it perfectly round," Zwierlein explained.
"In superfluids, as well as in superconductors, particles move in lockstep. They form one big quantum-mechanical wave," explained Ketterle. Such a movement allows superconductors to carry electrical currents without resistance.
The MIT team was able to view these superfluid vortices at extremely cold temperatures, when the fermionic gas was cooled to about 50 billionths of a degree Kelvin, very close to absolute zero (-273 degrees C or -459 degrees F). "It may sound strange to call superfluidity at 50 nanokelvin high-temperature superfluidity, but what matters is the temperature normalized by the density of the particles," Ketterle said. "We have now achieved by far the highest temperature ever." Scaled up to the density of electrons in a metal, the superfluid transition temperature in atomic gases would be higher than room temperature. Ketterle's team members were MIT graduate students Zwierlein, Andre Schirotzek, and Christian Schunck, all of whom are members of the Centre for Ultracold Atoms, as well as former graduate student Jamil Abo-Shaeer.
The team observed fermionic superfluidity in the lithium-6 isotope comprising three protons, three neutrons and three electrons. Since the total number of constituents is odd, lithium-6 is a fermion. Using laser and evaporative cooling techniques, they cooled the gas close to absolute zero.
They then trapped the gas in the focus of an infrared laser beam; the electric and magnetic fields of the infrared light held the atoms in place. The last step was to spin a green laser beam around the gas to set it into rotation. A shadow picture of the cloud showed its superfluid behaviour: The cloud was pierced by a regular array of vortices, each about the same size.
The work is based on the MIT group's earlier creation of Bose-Einstein condensates, a form of matter in which particles condense and act as one big wave. Albert Einstein predicted this phenomenon in 1925. Scientists later realized that Bose-Einstein condensation and superfluidity are intimately related.
Bose-Einstein condensation of pairs of fermions that were bound together loosely as molecules was observed in November 2003 by independent teams at the University of Colorado at Boulder, the University of Innsbruck in Austria and at MIT. However, observing Bose-Einstein condensation is not the same as observing superfluidity. Further studies were done by these groups and at the Ecole Normale Superieure in Paris, Duke University and Rice University, but evidence for superfluidity was ambiguous or indirect.
The superfluid Fermi gas created at MIT can also serve as an easily controllable model system to study properties of much denser forms of fermionic matter such as solid superconductors, neutron stars or the quark-gluon plasma that existed in the early universe.
SUPERFLUIDITY IN AN ULTRACOLD GAS OF FERMION ATOMS has been demonstrated in an experiment at MIT, where an array of vortices has been set in motion in a molecular Bose Einstein condensate (BEC) of paired lithium-6 atoms. There have been previous hints of superfluidity in Li-6, but the presence of vortices observed in the new experiment clinches the case since vortices manifest the most characteristic feature of superfluidity, namely persistent frictionless flow.
Wolfgang Ketterle and his MIT colleagues use laser beams to hold the chilled atoms in place and separate laser beams to whip up the vortices. In general the quantum behaviour of bosonic atoms (those whose total internal spin-the spin of the nucleus added to that of the electron retinue - is an integral number of units) and fermi atoms (those with a half-integral-valued total spin) is very different.
Gaseous Li-6 represents only the second known superfluid among fermi atoms, the other being liquid helium-3. (Superconductivity is also a form of fermion superfluidity, but in this case the constituents are charged particles, electrons, unlike the neutral atoms used in the experiments described here.) There are great advantages in dealing with a neutral superfluid in dilute gas form rather than in liquid form: in the gas phase (with a material density similar to that of the interstellar medium), inter-atomic scattering is simpler; furthermore, the strength of the pairing interaction can be tuned at will using an imposed external magnetic field.
According to Ketterle, one of those who won a Nobel prize for his pioneering work with boson BECs, the study of fermionic superfluidity is much richer than for bosons: control over forces will permit researchers to vary the strength and nature of the pairing (fermi atoms must pair up before falling into BEC form) and to load atoms into an optical lattice. Additional pairing mechanisms can also be explored.
One further superlative: the ultracold lithium gas represents, in a narrow sense, the first "high-temperature" superfluid.
Consider the ratio of the critical temperature (Tc) at which the superfluid transition takes place to the fermi temperature (Tf), the temperature (or energy, divided by Boltzmann's constant) of the most energetic particle in the ensemble.
For ordinary superconductors, Tc/Tf is about 10^-4; for superfluid helium-3 it is 10^-3; for high-temp superconductors 10^-2; for the new lithium superfluid it is 0.3.